Study finds ZnO nanorods achieve 98.3% Faraday efficiency in CO₂ reduction

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Nano-ZnO is a potential catalyst material for carbon dioxide electrocatalytic reduction (CO₂RR), but its effective Faraday efficiency (FE) is still below 90% and the current density is less than 300 mA cm^-2, which is not enough to meet industrial requirements.

A new study published in Chem Catalysis reported on ZnO nanorods for electrocatalytic CO₂RR, which after 500°C heat-treatment, achieved the highest oxygen vacancy content, the highest FE_CO of 98.3%, and a partial current density of 786.56 mA cm^-2 in a 3 M KCl electrolyte.

The research was conducted by Prof. Wu Zhonghua and Dr. Xing Xueqing from the Institute of High Energy Physics of the Chinese Academy of Sciences (CAS) and Prof. Han Buxing from the Institute of Chemistry of CAS.

The team used a series of advanced detection techniques, including synchrotron radiation X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, and electron paramagnetic resonance, to confirm the presence of oxygen vacancies. Density functional theory calculations showed that oxygen vacancies can not only change the d-band of ZnO, but also enhance the activity of CO₂.

Then, the researchers discussed the effect of oxygen vacancy on carbon dioxide electroreduction reaction by using electrochemical characterization methods. The results showed that oxygen vacancies provide excellent kinetic conditions for CO generation and play a key role in accelerating CO₂ activation and reducing the energy barrier of CO generation.

This study represents a breakthrough in catalyst materials for the electrocatalytic CO₂RR and highlights the potential of low-cost ZnO nanorods rich in oxygen vacancies as robust and efficient catalysts for CO₂RR, which are expected to facilitate the development of sustainable energy conversion technologies.

More information: Zhongnan Ling et al, Enhanced electrochemical reduction of CO₂ to CO by ZnO nanorods enriched with oxygen vacancies, Chem Catalysis (2024). DOI: 10.1016/j.checat.2024.101192

Journal information: Chem Catalysis

Provided by Chinese Academy of Sciences