New organic molecule design can lead to long-lasting, durable OLEDs for displays

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Absorption, fluorescence, delayed fluorescence, and phosphorescence of the investigated molecules. Credit: Nature Communications (2024). DOI: 10.1038/s41467-024-53740-1

Scientists have developed a method to improve the stability and efficiency of organic light-emitting diodes (OLEDs), a technology used in smartphones, TVs, and other electronic displays.

This advancement utilizes a unique type of molecule that has the potential to extend the lifespan of OLED devices significantly.

The researchers present a novel way to design organic molecules that can maintain their stability and efficiency over time, even in high-stress conditions. The research is published in the journal Nature Communications.

These new molecules represent a step change in our understanding of the very fundamental ideas about intramolecular charge transfer excited states. Conceptually, they break all our current ideas about these excited states and a totally new model linking molecular bonding patterns leading to the breaking of molecular pi-conjugation in the excited state has been developed in order to explain this new phenomena.

These molecules, termed "rigidly planar charge-transfer molecules," enable better triplet harvesting, a process that enhances the efficiency of OLEDs through thermally activated delayed fluorescence (TADF).

Unlike conventional OLED molecules, which tend to twist and lose stability, this new design maintains a stable structure, ensuring longer-lasting device performance.

OLED displays are praised for their vibrant colors and energy efficiency but often suffer from limited lifespans.

The new approach could make OLED devices that are more durable, reducing the need for frequent replacements. This breakthrough could also have implications beyond OLEDs, with potential applications in bio-imaging and photocatalysis, where stable, high-efficiency light emission is valuable.

More information: Suman Kuila et al, Rigid and planar π-conjugated molecules leading to long-lived intramolecular charge-transfer states exhibiting thermally activated delayed fluorescence, Nature Communications (2024). DOI: 10.1038/s41467-024-53740-1

Journal information: Nature Communications

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